Fundamental Laws of Chemistry
The Law of Conservation of Mass states that matter's mass remains unchanged during a chemical reaction. Reactants and products have equal total mass, meaning mass cannot be created or destroyed.
The Law of Definite Proportions (often called the Law of Definite Proportions) asserts that a chemical compound always contains its component elements in a fixed ratio by mass.
The Law of Multiple Proportions describes that when two elements form more than one compound, the mass ratios of the elements are simple whole numbers. Dalton observed that these ratios are small, whole‑number multiples.
Atomic Models: From Dalton to Rutherford
John Dalton’s first postulate described atoms as indivisible, solid particles. In contrast, J.J. Thomson’s Plum‑Pudding model introduced internal structure: a diffuse positive sphere containing embedded electrons.
Ernest Rutherford’s experiments with alpha particles revealed that most of an atom’s mass is concentrated in a dense nucleus, not in the electron cloud. This corrected the earlier misconception that the electron cloud held the majority of the mass.
Characteristics of Scientific Models
Scientific models share four key characteristics:
- Simple – they reduce complex reality to essential features.
- Human‑created – they are constructed by scientists to aid understanding.
- Testable – they must generate predictions that can be experimentally verified.
- Limited – they acknowledge what they cannot explain.
Subatomic Particles and Their Properties
A proton carries a charge of +1 and has a mass of approximately 1 atomic mass unit (amu). Neutrons are neutral particles that differ in number among isotopes of the same element. Electrons have a charge of –1 and a negligible mass relative to protons and neutrons.
When an atom loses two electrons, it acquires a 2+ charge, reflecting a positive ion.
Isotopes and Ions
An isotope is defined as atoms of the same element that have different numbers of neutrons. For example, the notation ^14_7N represents a nitrogen‑14 isotope with 7 protons and 7 neutrons (mass number 14, atomic number 7).
Isotopes differ from ions in that isotopes vary in neutron count while retaining the same elemental identity and charge. Ions, on the other hand, differ in electron count, resulting in a change of electrical charge.
The statement that "the mass number of an isotope equals the number of protons in the nucleus" is false; mass number equals the sum of protons and neutrons.
Atomic Number vs. Mass Number
The atomic number indicates the number of protons in an atom and uniquely identifies the element. The mass number is the total of protons plus neutrons, providing the atomic mass of a specific isotope.
Periodic Table Organization
The periodic table is arranged in order of increasing atomic number. Elements in the same group (vertical column) share similar chemical properties because they have comparable valence electron configurations.
Group 1A elements are commonly known as alkali metals. These metals are highly reactive and readily lose their single valence electron to form +1 ions.
Historical Highlights
J.J. Thomson coined the term “electron” in 1891 after observing cathode‑ray phenomena. The discovery of the neutron was credited to James Chadwick in 1932, completing the picture of atomic structure.
In Rutherford’s scattering experiments, a tiny fraction of massive alpha particles were deflected by small angles, while about 1 out of 20,000 were deflected by more than 90°, indicating the presence of a dense, positively charged nucleus.
Review Questions
- What law states that mass is conserved in chemical reactions?
- Identify the missing word in "Law of {{Definite}} Proportions".
- True or false: Elements in the same group have similar chemical properties?
- Contrast Dalton’s atomic view with Thomson’s Plum‑Pudding model.
- List the four characteristics of a scientific model.
- What is the charge and approximate mass of a proton?
- Define an isotope in terms of neutrons.
- Explain the difference between atomic number and mass number.
- Who discovered the neutron and in what year?
- Interpret the notation ^14_7N.


